1. Introduction
This paper is divided into three parts. The first part deals with some technical issues concerning Jefimenko’s equations, which are perhaps not completely clear from [1]. Namely that we can obtain solutions to Maxwell’s equations from a given charge and current configuration , satisfying the continuity equation, with vanishing at infinity, using Jefimenko’s equation to define the electric and magnetic fields . In particular, this is the case for localised charge and current configurations, or when the charge and current decays rapidly at infinity, a condition true for the Schwartz class of functions which we have denoted by and we have referred to as smoothly decaying. This result is applied in Lemma 5, where we construct satisfying Maxwell’s equations and various other relations, just from the assumptions that satisfies the wave equation, has a restriction on the initial condition, and belongs to the Schwartz class.
The second part of the paper is mainly concerned with deriving these relations, and proving a converse in the context of special relativity, that these relations are characterised by a no radiation condition in all inertial frames. In Lemma 3, we characterise the smoothly decaying solutions of the wave equation for electric fields, as well as the smoothly decaying electromagnetic solutions to Maxwell’s equations in free space. This requires a careful Fourier analysis, and, in particular, we require the smoothly decaying hypothesis to apply the inversion theorem. We conclude the Lemma by proving that if , then we can find a free space solution , such that . This result is required in Lemma 5.
In Lemma 4, we characterise and in terms of the quantities . Combining these last two Lemmas, we obtain the result of Lemma 5 mentioned above, that we can obtain a number of conditions on from essentially the assumption that satisfies the wave equation. In particularly, we can arrange for the magnetic field and Poynting vector to be both zero. In Lemma 6, we strengthen this result, to show that if we can obtain the relations of Lemma 5 for in the rest frame , then for any inertial frame , we can extend the transformed charge and current to , satisfying the same relations. This requires the transformation rules for quantities in , and we rely on the fact that the transformed quantities are bounded, which follows from the smoothly decaying hypothesis, to apply Liouville’s theorem.
These last two Lemmas are the basis for the non-radiating condition, which we formulate in Definition 2, that in any inertial frame we can arrange for a solution , extending the transformed quantities , with . This certainly ensures that the transformed system doesn’t radiate, according to the definition in [1], as the Poynting vector is zero. Interestingly, in Lemma 7, a converse is proved, namely that for any system satisfying the non-radiating condition, in the rest frame , and satisfy the wave equation, and we can obtain all the relations proved in Lemma 5. This suggests that the no-radiation condition might be enough to consider using wave equations for in atomic systems, which should not radiate according to Rutherford’s observation.
However, there are weaker definitions of non-radiation, which we give in Definition 3. Some of these we are able to exclude, while supporting our hypothesis, which we do in Lemmas 8 and 9, and, others exclusions we leave as conjectures. Certainly, a successful proof of these conjectures, which we believe might be possible with a careful analysis of the stress energy tensor, see [2], would be a compelling argument for the use of the wave equation in quantum theory, and we should make some comparisons. Although Schrodinger’s equation has a relativistic formulation in quantum field theory, through the use of the Klein-Gordon equation or the Dirac equation, it still lacks the relativistic invariance of the relations which we were able to derive, and, indeed, uses the possibility of radiating atomic systems to account for the Lamb shift in the hydrogen spectrum. We believe this shift might be accounted for in the discussion of the final part of the paper, and still believe that radiative behaviour would be a strange property. For example, the radiated energy would have to oscillate, if the system is to remain stable, and we do not observe this behaviour in the Lamb shift. Another important point to make here is that, if energy is radiated locally in the system, , then, assuming that locally work is done on electrons in the system, the condition , we can obtain a transfer of heat from electrons in one part of the system to another. If we impose a condition of thermal equilibrium and expect that the system does not radiate to infinity, necessary to counter Rutherford’s observation, we can obtain a violation of the second law of thermodynamics. We save this point of view for another occasion, the reader might be interested in [3], which considers cavity radiation on a fairly qualitative level. A successful resolution of these issues is clearly required and we believe that we have made a step in the right direction.
In the last part of this paper, we deal with a common criticism of classical electromagnetism, in it’s failure to explain quantised phenomena, in particular the behaviour of the Balmer series or the results of the Franck-Hertz experiment. In Lemma 10, we start with the relations of Lemma 5, and characterise these relations in terms of the coefficients governing the Fourier expansions of and , a coefficient relation which we later refer to as a radial transform condition. In Lemma 11, we show that these relations can be obtained while also imposing the condition that , a natural requirement for an atomic system. This introduces a discreteness phenomena in terms of the zeroes of Bessel functions vanishing at and, in Lemma 12, we prove a technical result on how these functions, combined with the spherical harmonics, provide an orthogonal basis for smooth functions on the ball , vanishing at the boundary.
In Lemma 13, we compute the energy stored in the electromagnetic field, when restricted to , and find, that when the total charge confined to the ball is non-zero, we are able to remove the one continuous degree of freedom, to obtain quantisation of the energy values, in line with the Balmer series, see [4]. The ionisation condition, on the total charge confined to the ball, seems quite interesting, and is observed in the Frank-Hertz experiment. Again, some comparative remarks should be made, namely the success of Schrodinger’s equation, together with Bohr’s atomic model, in accounting for the Balmer series. We were not able to verify the value of the Rydberg constant in this paper, due to computational issues, but we emphasise that we were able to get the dependence, where is an integer. Possibly, further computations of Bessel functions and spherical harmonics can be done to resolve this issue, and, again, we believe that we have gone some way to answering this potential criticism of the use of the wave equation. We believe there is some scope for developing the classical theory here, without relying on Planck’s photonic theory of radiation, in how the system switches between electromagnetic energy levels, and in how light of certain energies, which we propose would come from the differences in these energy levels, is emitted.
We make some observations which are not part of this paper, but instead direct the reader to further work. A principle justification for using the Schrodinger equation is its reliance on wave-particle duality. This requires that an electron can simultaneously be both a particle and a guiding wave, modelled on the square of the wave function . The particle nature of the electron can be observed in experiments such as Millikan’s deflection or Compton scattering, while the wave nature, can be seen in the interference patterns of electron diffraction, see [4]. However, it seems that a dual nature which explains these experiments is a failure to find a better explanation, with the cost of developing a rather paradoxical theory. Instead, a wave function, modelling the behaviour of charge and current, and linking directly with classical electromagnetism, has been proposed here.
The author believes that, using nonstandard analysis, one can develop the idea of the wave being composed of individual infinitesimal entities, which behave as particles, and propagate independently, with trajectories determined by a charge and current satisfying the continuity equation. Some successes for this viewpoint can be found in [5], where the heat equation solution is modelled as a random diffusion, and [6], where the nonstandard wave equation is shown to perfectly approximate the wave equation at standard values. Instead of considering individual velocities and momenta, one can instead compute the distribution of these quantities, and some unfinished progress in this direction has been made for the diffusion equation in [7]. A similar idea is present in Boltzmann’s derivation of the distribution of molecular speeds for ideal gases. In the case of the wave equation satisfying additional conditions which we have examined, we expect a sharp peak in the distribution function, as would be expected from a single particle. Similar consideration might apply to photons.
We finally mention the theory of black body radiation, developed by Planck, and explained concisely in [8]. A criticism of classical electromagnetism has been its failure to explain the spectrum of black body radiation, by postulating that the radiated energy is independent of frequency, often referred to as the ultraviolet catastrophe. A central concept used in the experimentally successful resolution of this problem, was Planck’s use of the quantisation of particular energies of molecular systems. The author hopes that the present paper goes some way to assuage these criticisms, without abandoning the main component of Planck’s argument in quantum statistical mechanics.
2. Jefimenko’s Equations
We begin this paper by first clarifying a technical issue surrounding Jefimenko’s equations.
Lemma 1.
Suppose that satisfy Maxwell equations, for given charge and current , and the potentials , with;
and
are chosen to satisfy the Lorentz gauge condition;
Suppose that also satisfy the Lorentz gauge condition, with the additional equations;
Then the corresponding fields still satisfy Maxwell’s equations for the same charge and current .
Proof.
It follows from [1] that satisfy the Equations (1) and (2) from the lemma. Let , , then satisfy the equations;
and the Lorentz gauge condition. Let be the corresponding fields. Then, it is sufficient to show that they satisfy Maxwell’s equation in vacuum;
For (5), we have, using the definition of , the Lorentz gauge condition, and condition (3) that;
For (6), we have, using vector analysis, see [
9];
For (7), we have, using the definition of , and vector analysis, see [
9], that;
For (8), we have, using the definition of and condition (4) that;
A simple calculation shows that;
where;
whereas, using the definition of ;
It is, therefore, sufficient to prove that;
where;
This holds, using the Lorentz gauge condition, as;
Lemma 2.
Let the potentials be defined be given as retarded potentials;
then, assuming satisfy the continuity equation and vanishes at infinity, these potentials satisfy the Lorentz gauge condition and the equations in the hypotheses (1) and (2) from Lemma 1. In particular, the corresponding fields , given by Jefimenko’s Equations;
satisfy Maxwell’s equations.
Proof.
The first part of the claim, under the stated hypotheses, is proved in [1], p424, see also footnote 2 of that page and Exercise 10.8, with the solutions given in [10]. For the final part of the claim, one can assume the existence of a solution to Maxwell’s equations, then construct potentials abstractly, satisfying the Lorentz gauge condition, as is done in [1]. Applying the result of Lemma 1, we obtain the result. Alternatively, one can verify Maxwell’s equations directly, for , using the method of Lemma 1, just replacing the conditions (3) and (4) on , in the proof, with their non-homogeneous versions. The fact that the fields are given by Jefimenko’s equations is proved in [1], p427-428.
Remark 1.
There is an alternative strategy to construct explicit solutions for , given the corresponding fields , satisfying Maxwell’s equations, and the potentials satisfying the Lorentz gauge condition. Namely, one can use the explicit formulas, suitably rescaled, for solutions to the homogeneous and inhomogeneous wave equations given in [11], (p73 formula (22) and p82 formula (44)) respectively, with the initial conditions given by and the driving terms given by . In the context of Lemma 2, one can easily compute the initial conditions, and, in principle derive new formulas for , replacing the retarded potentials, and for , replacing Jefimenko’s equations.
3. A No Radiation Condition
We now clarify some results about smoothly decaying solutions to Maxwell’s equations in free space.
Definition 1.
By Maxwell’s equations in free space, we mean;
- (i) ,
- (ii) ,
- (iii) ,
- (iv) .
We abbreviate the operator by .
Lemma 3.
The smoothly decaying solutions of the wave equation are given by;
where ,
while the smoothly decaying solutions of Maxwell’s equations in free space, are given by;
where , and where , , , and ,
where , , ,
.
Finally, if is a smoothly decaying solutions of the wave equation , there exists a pair which is a smoothly decaying solution of Maxwell’s equations in free space, such that;
Proof.
It is easily checked that the solutions (9) and (10) satisfy (i)-(iv) of Definition 1.
Conversely, let be smooth solutions of (i)-(iv). We have, using (i), (iii) and (iv), that;
and, hence;
and
If solve the wave equation, , where , for , then;
by the inversion theorem of Fourier analysis, see [11] and [12]. Hence
and
So that
using the inversion formula again.
as
and
where , as required for the first part. Using , we have that
At and , we obtain that
which implies
As this holds for all , using the inversion formula, we obtain
and
Assuming , we obtain
,
so that
,    and the first part of the result (9) follows.
Using the same argument, we obtain that
Using (iii);
where , , and , using (11).
This proves the second part of the result. For the final part, we can use the first part to write
where . For , let
and
Then , and we can write
with and
so that
with .
It follows that we can write
Similarly, repeating the procedure for , we can write
We set
We need to check that if is real, then so is . If , then, using (13) and equating coefficients, we have
and .
It follows that
and, similarly , so that is real, and, therefore, is real.
Using the second part, we can find such that is a smoothly decaying solution of Maxwell’s equations in free space. Finally, we compute
as required.
Lemma 4.
Let satisfy Maxwell’s equations, then
and
Proof.
As is done in [1], we can choose potentials such that
and satisfy the Lorentz gauge condition. It follows, see Lemma 1, that satisfy the equations
and
It is an easy exercise in vector calculus to show that commutes with the gradient operator , the curl operator and partial differentiation . Therefore, we compute
and
Lemma 5.
Let satisfy the wave equation , with the initial conditions and , then there exists such that satisfies the continuity equation, satisfies the wave equation with , and such that satisfy Maxwell’s equations, with and . In particular, the Poynting vector .
Proof.
Define by
.
Then, by the fundamental theorem of calculus, we have . In particular,
Applying the divergence operator, differentiating under the integral sign, using the wave equation for , we have
Choose so that , then , so that satisfy the continuity equation. By the initial conditions, that and belongs to the Schwartz class, the general solution of the homogeneous wave equation with initial conditions, see [
11], and an appropriate choice of , we have that vanishes at infinity. It follows, applying the result of Lemma 2, that we can find a pair , such that satisfy Maxwell’s equations, and, by the result of Lemma 4 and the condition (14), we have that , so that also satisfies the wave equation. Moreover, by the explicit formulas in Jefimenko’s equations, one can check that is also smoothly decaying. Then, using the result of Lemma 3, we can find , which are smoothly decaying solutions of Maxwell’s equations in free space and with , (13). Clearly, still satisfy Maxwell’s equations, and, by (13) and Maxwell’s equations, we have
that is the field is magnetostatic. Set , then satisfy Maxwell’s equations, so that, subtracting solutions, also satisfies Maxwell’s equations. We must have then that satisfies the continuity equation. As were solutions to Maxwell’s equations in free space, we have , so that, as , we must have as well. By Lemma 4, we have
By elementary vector calculus, (15), the continuity equation, the fact that , and the first result of Lemma 4, we have
so that . This proves the main claim. The fact that the Poynting vector is zero follows trivially from the fact that the magnetic field vanishes.
We now strengthen this result.
Lemma 6.
Let satisfy the conclusions of Lemma 5, then in any inertial frame moving with velocity vector relative to , if are the transformed charge distribution and current, there exists a pair such that satisfy Maxwell’s equations in , and with in . In particular, the Poynting vector . Moreover, the pair still satisfy the wave equations and , with .
Proof.
Let be the transformed quantities in , corresponding to in . The transformation rule for the electric field, see [13], is given by
where and denote the parallel and perpendicular components respectively. Note that is defined in the equation by , and by . As , from the assumption that in , we have that an observer in
sees the electric field
Let be the d’Alembertian operators in , then using the Lorentz invariance of the d’Alembertian operator, the obvious fact that it commutes with parallel and perpendicular components, the above transformation rule, and the fact that , we have
Similarly the transformation rule for the magnetic field, see [13], is given by
which, using the fact that in again, becomes
Using, a similar argument to the above, this time using the fact that the d’Alembertian commutes with taking a cross product with , we have
As in Lemma 5, and using the last part of the result of Lemma 3, with the fact that , we can find a pair which are smoothly decaying solutions of Maxwell’s equation in free space, and with
Then clearly, we still have that
and, moreover, by Maxwell’s equations in and (16)
so that is magnetostatic. However, we then have
so that satisfies Laplace’s equation and is harmonic. Using the fact that is bounded, we can use Liouville’s theorem to conclude that is constant, and using the fact that vanishes at infinity, that in fact . Setting and then gives the first result. The result about the Poynting vector is clear. Finally, we have the transformation rules for current and charge, see [
13], given by
and
where and . We then compute, using the usual commutation rules, the transformation rules just given, and the fact that and in , that
and
Finally, the fact follows from the result and the second result in Lemma 4.
We now prove a kind of converse to this result. We first require the following definition:
Definition 2.
Let be a charge distribution and current, satisfying the continuity equation in the rest frame . Then, we say that is non-radiating if in any inertial frame , with velocity vector , for the transformed current and charge , there exist electric and magnetic fields in such that satisfy Maxwell’s equations in and with .
Lemma 7.
Let , as in Definition 2, be non-radiating, then satisfy the wave equations and .
Proof.
By the definition of non-radiating, there exist fields in the rest frame such that satisfy Maxwell’s equations and . We then have that and, by the second result in Lemma 4, that . By the same argument, and using the definition of non-radiating, we must have that for the transformed current and charge in any inertial frame with velocity vector . We now compute . We have, as above, the transformation rule for given by
so that, using elementary vector calculus;
We also have, see [13], the transformation rule for ;
Taking , we have , , , and so that
while
and
Combining these results, it follows that
As we have seen, in . In coordinates, this implies that
It follows that
As is arbitrary and , we conclude that
Taking the divergence of (17) and using the continuity equation, we obtain that
so that . We can conclude as in Lemma 5, using (17), the continuity equation and the fact that , that as required.
We make a further definition;
Definition 3.
Let be a charge distribution and current, satisfying the continuity equation in the rest frame . Then, we say that is strongly non-radiating if in any inertial frame , with velocity vector , for the transformed current and charge , there exist electric and magnetic fields in such that satisfy Maxwell’s equations in and with . We say that is mixed non-radiating if in any inertial frame , with velocity vector , for the transformed current and charge , there exist electric and magnetic fields in such that satisfy Maxwell’s equations in and with either or . We say that is Poynting non-radiating if in any inertial frame , with velocity vector , for the transformed current and charge , there exist electric and magnetic fields in such that satisfy Maxwell’s equations in and with the Poynting vector . We say that is surface non-radiating if in any inertial frame , with velocity vector , for the transformed current and charge , there exist electric and magnetic fields in such that satisfy Maxwell’s equations in and with .
We note the following;
Lemma 8.
Let be strongly non-radiating, then is trivial, that is and .
Proof.
In the rest frame , we can find a pair such that satisfy Maxwell’s equations and with . By Maxwell’s equations, we have that , so that
In an inertial frame , with velocity vector , we have, by the transformation rules and (18), that;
Using the fact that we can find such that satisfy Maxwell’s equations and with , we can conclude again, that . By (19), we then have that , so that , for every velocity vector . This clearly implies that as required.
Lemma 9.
Let be mixed non-radiating, but not non-radiating, then is trivial, that is and .
Proof.
Without loss of generality, using the result of Definition 3, we can assume that in the rest frame , there exists a pair such that satisfy Maxwell’s equations and with , and that there exists an inertial frame , with velocity vector , such that, for the transformed charge and current , there exists a pair such that satisfy Maxwell’s equations and with . Working in the rest frame , we have that, by Maxwell’s equations, , so that . As , we have by Lemma 4, that;
so that is static. Again by Maxwell’s equations, we have that;
so that, as , is static, and
Switching to the frame , using the fact that and the second result of Lemma 4, we have that . Repeating the calculation of Lemma 7, and using the fact that , we have that;
It follows that;
so that;
and
By the second result of Lemma 4, we obtain that , but is static, so in fact . Applying Liouville’s theorem, and using the fact that is bounded and vanishing at infinity, we obtain that . From (20), we must have that as well, proving the claim.
Remark 2.
We conjecture that if are Poynting or surface non-radiating, but not non-radiating, then are trivial. Given these conjectures, if an electromagnetic system fails to satisfy the wave equation outline above, then in some inertial frame, without loss of generality, we would have that on some open . By the divergence theorem, this would imply an energy flux through the boundary of . This imposes strong restrictions on the nature of this flux, as if the total energy of the system were to reduce to zero, or even decrease then, we can consider Rutherford’s observation, that, in an atomic system, the orbiting electrons would spiral into the nucleus.
4. The Balmer Series
We now consider flows satisfying the wave equation.
Lemma 10.
Let be a pair, satisfying the continuity equation, with , and the wave equations and , with the additional equation;
Then if
and
we have that, for ;
If is tangential, that is for , and , , then the pair is trivial, that is and .
Proof.
By the first part of Lemma 3, using the fact that and satisfy the wave equation, we can write;
and
where , and .
We have that;
while;
so that, equating coefficients, using the Inversion Theorem, and (21), we have that;
We have that;
and
so that, equating coefficients again, and using the continuity equation , we have;
Now suppose that is tangential. We then have, applying the Fourier transform , see [
11];
so that which implies, equating coefficients, that . Using the formula (22), we have;
so that;
In coordinates, this would imply that;
so that and . Similarly, we conclude that , and, using the equations (22), that . This implies that and as required.
Lemma 11.
We can find a pair satisfying the hypotheses of Lemma 10, with the additional requirement that .
Proof.
We convert to spherical polar coordinates, , , , for , , writing the Laplacian;
where
and
are the radial and angular components respectively. The eigenvectors of the operator are the spherical harmonics, defined by;
and
where
, and
, ,
see the appendix of [
14]. We have that forms a complete orthonormal basis of , and, moreover
see the appendix of [
14] again. We look for eigenvectors of of the form . We have, using (24), that
so that
iff satisfies the radial equation;
We can solve (26), using the method of Frobenius, see [
15], but the solutions are only bounded for , and making the change of variables , the radial equation reduces to the spherical Bessel equation;
which, as noted in [
14] has a unique bounded solution (up to scalar multiplication) on defined by;
where denotes the ordinary (of the first kind) Bessel function of order . As is shown in [
14] again, see also [
16], the functions;
form a complete orthonormal set in . Moreover, we have the explicit representations;
where are polynomials of degree , with the property that and , for , see [
17].
We set
and
where for . By what has been shown forms a complete orthonormal set, (9), and . It follows easily, that we can write a general solution for the charge and current contributions in the wave equation using the forms;
We say that satisfies the radial transform condition, if, in the notation of Lemma 10, we have that, for ;
for some . As is easily shown, if satisfies the radial transform condition, then if we define according to the second pair of equations in Lemma 10, we automatically have that satisfies the first pair, and all the assumptions of Lemma 10 are met. By considering the representation of in Lemma 10, equating coefficients, and applying the inversion theorem, we see that;
for . We compute these integrals using the representation of in (28) and the representation;
given in [
14], where . We have, using the property (9), that;
A similar calculation shows that;
It follows from (29) that;
We can compute in spherical harmonics by;
noting that, by orthonormality of the spherical harmonics;
Equating coefficients, the radial transform condition is satisfied setting;
where , and , , .
We now impose the boundary condition, that . We can achieve this by requiring that
, or equivalently, that , or . The positive zeros of form a discrete set and we require that . Using the asymptotic approximation;
given in [
14], we have
for large values of . Using (28), we have that takes the form;
where we have that;
for some nonstandard infinite and the coefficients are chosen to satisfy (32) at the discrete eigenvalues.
Remark 3.
Technically, the calculation (30) requires smoothness of the coefficients in the continuous variable , so that we can invoke the Riemann-Lebsegue lemma, to eliminate the orthogonal terms . When passing to a discrete sum, we lose this property, and, an argument involving equating coefficients is required. We have sketched over this by involving a nonstandard element , but, if the reader is unfamiliar with this circle of ideas, we are essentially using distributions. As this is primarily a Physics paper, we leave the technical details for another occasion.
Lemma 12.
Let , where , then, for , , fixed, forms a complete orthonormal system in , consisting of continuous functions on the interval , vanishing at , with respect to the measure . Moreover, the functions , for ,, form a complete orthonormal system in , consisting of continuous functions on the ball of radius , vanishing at the boundary , with respect to the standard measure .
Proof.
Let
and
so that
for . By Lagrange’s identity, see [15], we have that
and, with notation as above, we have
.
As , we have applying (35), that
Clearly, if are distinct, this proves that and are orthogonal with respect to the measure . We then have, using l’Hospital’s rule, assuming that and the recurrence relation for Bessel functions, see [
14];
It follows immediately, that, for fixed , the form an orthonormal system. The proof that the form a complete system is sketched in [
18]. As forms an orthogonal system on , we have that;
proving that the form an orthonormal system. Completeness then follows easily from completeness of the and the .
Lemma 13.
For the fundamental electric field solutions , as defined below, the corresponding time averaged energies , determined by the conserved quantity , defined below, are quantised and display the properties of the Balmer series. Moreover, for a general bounded electric field solution , determined by , satisfying the hypotheses of Lemma 11, the corresponding energy can be computed in terms of the fundamental energies.
Proof.
We compute the electric field , assuming the magnetic field vanishes. By Maxwell’s equations;
so that, integrating (33) of Lemma 11, requiring the boundedness condition, using the result of Lemma 12, and the relations, (34) of Lemma 11, we have;
From here, we rely on the fact, proved in [
18], that for distinct, the Bessel functions and have no common zeros. We define the fundamental solutions , , by requiring that and are both supported at a single point of the discrete union , so that;
and both and are defined by (32), in Lemma 11. By Poynting’s Theorem, see [
1], using the facts , (32) of Lemma 11, and the coefficient relations in Lemmas 10 and 12, the total energy stored in the electric field , restricted to , is given by;
where .
Now let
.
Note that is conserved, as, by the continuity equation, the divergence theorem, and the vanishing of on ;
Using the relations and from Lemma 10 and the radial condition, we have, using the integral representation in Lemma 10, that for a fundamental solution;
We can then use this representation, the result in [
19], together with the conservation property, to obtain;
so that, rearranging ,    , and, for ;
Now we can substitute in (38), to obtain;
and, taking the average over a cycle;
By the explicit representation of Bessel functions in Lemma 11, we have that;
and, using the asymptotic description of for large values of , in Lemma 11, we have that;
So that, for even;
and, for odd;
It follows that, for even, and large ;
and for odd, and large ;
where and , and , with ,
which agrees closely with the Balmer series as claimed. Observe that for distinct and , using the representation (37) and the orthogonality of the series , that for and supported on and respectively, that;
For any represented as in (36) we have that;
where and are the restrictions of and to . It follows from (39) and (40), that;
where .
Remark 4.
Note that the condition places no restriction on the values of and , when . As the values of and can vary continuously, this suggests that the quantisation phenomenon, observed in the previous lemma, occurs only when the atom is ionised, in which case and we observe the behaviour of the Balmer series. This point of view is supported by the results of the Franck-Hertz experiment.
Conflicts of Interest: 
“The author declares no conflict of interest”.